Asymmetric Hydrogenation of Acetophenone by Rh(I)-BINAP Supported on Smectites with Various Interlayer Distances

Chiral ferrocenyl diphosphines for asymmetric transfer hydrogenation of acetophenone

The synthesis of new optically pure ferrocenyl diphosphines have been realized from (R)-(+)-N,Ndimethylaminoethylferrocene. Particularly, dissymmetric ferrocenyl diphosphines have been synthesized. The diphosphines have been used as ligands in asymmetric transfer hydrogenation of acetophenone in the presence of Ru catalysts. © 2006 Elsevier Science. All rights reserved ——— * Corresponding autho...

Origins of enantioselectivity in asymmetric ketone hydrogenation catalyzed by a RuH2(binap)(cydn) complex: insights from a computational study.

In this paper, the origins of enantioselectivity in asymmetric ketone hydrogenation catalyzed by RuH(2)(binap)(cydn) (cydn = trans-1,2-diaminocyclohexane) were discussed. Fifteen substrates involving aromatic, heteroaromatic, olefinic and dialkyl prochiral ketones were used to probe the catalytic mechanism and find an effective way to predict the chirality of the products. The calculated result...

Dynamic Analysis of Asymmetric Structures Supported by a Sliding Foundation

Dynamic Analysis of Asymmetric Structures Supported by a Sliding Foundation

On asymmetric distances

In this paper we discuss asymmetric length structures and asymmetric metric spaces. A length structure induces a (semi)distance function; by using the total variation formula, a (semi)distance function induces a length. In the first part we identify a topology in the set of paths that best describes when the above operations are idempotent. As a typical application, we consider the length of pa...